Nitrogen oxides (NOx/NO2), NOx/NO2
Nitrogen oxides (NOX/NO2)
Nitrogen oxides (NOX) is the collective name for nitrogen monoxide (NO) and nitrogen dioxide (NO2)1 2. NO is a colourless, poisonous and odourless gas whereas NO2 is a reddish to brown poisonous gas with a sharp, pungent odour3.
Nitrogen dioxide is used as a potent oxidation agent in various chemical processes within industry. Nitrogen dioxide is also used in industrial production of nitric acid4 5 6.
Sources and transportation pathways
Nitrogen oxides are formed when nitrogen and oxygen react at high temperatures. Emissions of nitrogen oxides are therefore strongly connected to combustion processes7. Nitrogen oxides are emitted to air, where it reacts (to nitrate or nitric acid) and is deposited to land8. The reaction may occur both before and after deposition9. Nitrogen oxides contribute, together with volatile organic compounds (NMVOC) and sunlight, to formation of ground level ozone.
Examples of natural sources of nitrogen oxides are forest fires and lightning10. In Sweden the transport sector is the single largest source of nitrogen oxides11. Of the large point sources, the pulp and paper industry, energy industries and the metal industry are the main contributors to national emissions12.
Effects on environment and health
Deposition of nitrogen oxides results in acidification and eutrophication of land and water13. Acidification harms plants and animals, both on land and in water14. When the ground turns acidic, vital nutrients are leached from the soil, which eventually may result in reduced forest growth. Furthermore, metals are released in the ground that can harm decomposing organisms in the ground as well as birds and mammals higher up in the food chain, including humans15. Eutrophication occurs when there is an excess of nutrients (e.g. nitrogen) in land or water 16. The abundance of nutrients threatens biological diversity by allowing species that thrive in a nutrient-rich environment to outcompete species that are adapted to a more nutrient-poor environment 17.
Ground level ozone may damage vegetation and during episodes of high levels, humans may be affected by irritation of the respiratory tract18. Nitrogen oxides are poisonous and may irritate the respiratory tract and mucosal membranes.19 Epidemiological studies have shown an increase of symptoms of bronchitis in asthmatic children in connection with long-term exposure to nitrogen dioxide20.
International agreements and regulations
Nitrogen oxides are regulated by the UN Convention on Long-range Transboundary Air Pollution (CLRTAP) and the UN Framework Convention on Climate Change (UNFCCC) as well as by the EU National Emissions Ceilings Directive (2001/81/EC), the EU Air Quality Directive (2008/50/EC) and the EU Industrial Emissions Directive (2010/75/EU). The UN Protocol on PRTRs and the EU E-PRTR regulation regulate how data on nitrogen oxide emissions is made available.-----------------------------------------------------
1 http://www.naturvardsverket.se/Sa-mar-miljon/Statistik-A-O/Kvaveoxid-till-luft/2 http://www.norskeutslipp.no/no/Komponenter/Utslipp/Nitrogenoksider/?ComponentType=utslipp&ComponentPageID=159&SectorID=903 http://www.ne.se/uppslagsverk/encyklopedi/l%C3%A5ng/kv%C3%A4veoxider4 http://www.npi.gov.au/resource/oxides-nitrogen-05 http://prtr.ec.europa.eu/#/pollutantinfo6 http://www.norskeutslipp.no/en/Components/Emission/Nitrogen-oxides/?ComponentType=utslipp&ComponentPageID=159&SectorID=907 http://www.naturvardsverket.se/Sa-mar-miljon/Klimat-och-luft/Luftfororeningar/Kvaveoxider/8 https://www.naturvardsverket.se/Documents/publikationer/91-620-8089-X.pdf?pid=38799 https://www.naturvardsverket.se/Documents/publikationer/91-620-8089-X.pdf?pid=387910 http://www.npi.gov.au/resource/oxides-nitrogen-011 http://www.naturvardsverket.se/Sa-mar-miljon/Statistik-A-O/Kvaveoxid-till-luft/12 http://www.naturvardsverket.se/Sa-mar-miljon/Klimat-och-luft/Luftfororeningar/Kvaveoxider/13 http://www.naturvardsverket.se/Sa-mar-miljon/Klimat-och-luft/Luftfororeningar/Kvaveoxider/14 https://www.eea.europa.eu/publications/air-quality-in-europe-201615 http://www.airclim.se/f%C3%B6rsurningens-effekter16 https://www.eea.europa.eu/publications/air-quality-in-europe-201617 http://www.miljomal.se/sv/Miljomalen/7-Ingen-overgodning/18 http://www.miljomal.se/Miljomalen/Alla-indikatorer/Indikatorsida/?iid=104&pl=119 http://www.naturvardsverket.se/Sa-mar-miljon/Klimat-och-luft/Luftfororeningar/Kvaveoxider/20 http://www.who.int/mediacentre/factsheets/fs313/en/